Carbon–Nitrogen Bond Formation by the Reaction of 1,2‐Cumulenes with a Ditantalum Complex Containing Side‐On‐ and End‐On‐Bound Dinitrogen
Identifieur interne : 000D49 ( Main/Exploration ); précédent : 000D48; suivant : 000D50Carbon–Nitrogen Bond Formation by the Reaction of 1,2‐Cumulenes with a Ditantalum Complex Containing Side‐On‐ and End‐On‐Bound Dinitrogen
Auteurs : Joachim Ballmann ; Alyssa Yeo ; Brian O. Patrick ; Michael D. Fryzuk [Canada]Source :
- Angewandte Chemie [ 0044-8249 ] ; 2011-01-10.
Abstract
[2+2]‐Cycloadditionen an N2: Die η1:η2‐koordinierte N2‐Einheit des abgebildeten zweikernigen Tantalkomplexes reagiert mit 1,2‐Cumulenen wie Carbodiimiden, Schwefelkohlenstoff und Isothiocyanaten unter Bildung von neuen Kohlenstoff‐Stickstoff‐Bindungen.
Url:
DOI: 10.1002/ange.201005704
Affiliations:
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